The PAMS + Non-Methane Direct Measurement Integrated Online Monitoring System (GC-FID) for ambient air is a highly integrated monitoring system for volatile organic compounds (VOCs) in the environment. It employs self-developed electronic cryogenic technology to enrich and inject samples from the ambient air. The pre-concentration system does not contain any adsorbents and does not require liquid nitrogen; instead, it achieves the cooling effect of liquid nitrogen through electric power, with an effective temperature lower than -130°C. The system is equipped with dual analytical units that effectively conduct online analysis of 57 components of PAMS and total non-methane hydrocarbons, providing reliable and accurate data support for ozone pollution prevention and control efforts.